Just paste the following code on your functions.php file:
function email_members($post_ID) {
global $wpdb;
$usersarray = $wpdb->get_results("SELECT user_email FROM $wpdb->users;");
$users = implode(",", $usersarray);
mail($users, "New WordPress recipe online!", 'A new recipe have been published on http://www.wprecipes.com');
return $post_ID;
}
add_action('publish_post', 'email_members');
Once saved, all registered users will receive an email when a new post is published.
This recipe is inspired from an example found in WordPress Codex.
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How to: Automatically notify your members on new posts